Synthesis, characterization and cytotoxicity of bis(bipyridine) ruthenium(II) complexes with picolinic acid derivatives

Abstract

Bis(bipiridin)rutenijum(II) kompleksi (1-5) opšte formule [Ru(L)(bpy)2]PF6, gde je bpy = 2,2′-bipiridin; HL = 3-metilpiridin-2-karboksilna kiselina (HL1), 6-metilpiridin-2-karboksilna kiselina (HL2), 5-bromopiridin-2-karboksilna kiselina (HL3) 6-brompiridin-2-karboksilna kiselina (HL4) i piridin-2,4-dikarboksilna kiselina (HL5) su sintetisani i potpuno okarakterisani. Za jedinjenja 3, 4 and 5 urađena je difrakcionom analizom X-zraka na monokristalu...

Bis(bipyridine)ruthenium(II) complexes (1-5) of general formula [Ru(L)(bpy)2]PF6, where bpy = 2,2′-bipyridine; HL = 3-methylpyridine-2-carboxylic acid (HL1), 6-methylpyridine-2-carboxylic acid (HL2), 5-bromopyridine-2-carboxylic acid (HL3) 6-bromopyridine-2-carboxylic acid (HL4) and pyridine-2,4-dicarboxylic acid (HL5) were synthesized and fully characterized. For compounds 3, 4 and 5 single-crystal X-ray diffraction analyses were also performed...