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Primena faznih transformacija cezijum-izmenjenih zeolita za dobijanje stabilnih cezijum-aluminosilikatnih kristalnih struktura, CsAISi5O12 i CsAISi2O6 - potencijalnih matrica za imobilizaciju jona cezijuma

Phase transformations of cesiumexchanged zeolites for obtaining stable cesium aluminosilicate crystalline structures, CsAlSi5O12 and CsAlSi2O6 potential matrices for the immobilization of cesium ions

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Disertacija.pdf (3.449Mb)
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Author
Omerašević, Mia
Mentor
Dondur, Vera
Committee members
Matović, Ljiljana
Vukelić, Nikola
Nedić-Vasiljević, Bojana
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Abstract
Ispitan je mehanizam visoko temperaturskih faznih transformacija cezijum (Cs) izmenjenih zeolita tipa LTA i klinoptilolita (CLI). Analizirane su osobine dobijenih faza u pogledu termalne stabilnosti i otpornosti na luţenje jona cezijuma. Rezultati pokazuju da su dobijene stabilne kristalne alumosilikatne strukture polucita (CsAlSi2O6) i faze CAS (CsAlSi5O12) koje mogu biti matrice za imobilizaciju Cs jona...
The mechanism of high-temperature phase transformation of cesium (Cs) exchanged zeolites such as LTA and clinoptilolite (CLI) was investigated. Thermal stability of obtained phases and their resistance to Cs ion leaching was also analysed. It was shown that the obtained stable, crystalline alumosilicate structures of pollucite (CsAlSi2O6) and CAS phase (CsAlSi5O12) can be used as matrices for Cs ion immobilisation...
Faculty:
Универзитет у Београду, Факултет за физичку хемију
Date:
20-10-2017
Keywords:
jonska izmena / ion exchange / Na/Cs-LTA / Cs-clinoptilolite / phase transformation / sintering / hot pressing / pollucite / CAS phase / Na/Cs-LTA / Cs-klinoptilolit / fazne transformacije / sinterovanje / toplo presovanje / polucit / CAS faza
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Handle
https://hdl.handle.net/21.15107/rcub_nardus_8944
URI
https://nardus.mpn.gov.rs/handle/123456789/8944
http://eteze.bg.ac.rs/application/showtheses?thesesId=5427
https://fedorabg.bg.ac.rs/fedora/get/o:16805/bdef:Content/download
http://vbs.rs/scripts/cobiss?command=DISPLAY&base=70036&RID=49632783

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