Show simple item record

Complexes of Co(III), Ni(II) and Cu(II) with hydrazones of some 2-pyridyl-ke-tones

dc.contributor.advisorLeovac, Vukadin
dc.contributor.advisorBogdanović, Goran
dc.contributor.otherJovanović, Ljiljana
dc.contributor.otherBogdanović, Goran
dc.contributor.otherMészáros, Szécsényi Katalin
dc.contributor.otherVojinović-Ješić, Ljiljana
dc.contributor.otherJoksović, Milan
dc.contributor.otherLeovac, Vukadin
dc.creatorRodić, Marko
dc.date.accessioned2020-07-03T13:46:19Z
dc.date.available2020-07-03T13:46:19Z
dc.date.issued2015-12-01
dc.identifier.urihttp://www.cris.uns.ac.rs/DownloadFileServlet/Disertacija144707949315176.pdf?controlNumber=(BISIS)95722&fileName=144707949315176.pdf&id=4583&source=NaRDuS&language=srsr
dc.identifier.urihttps://nardus.mpn.gov.rs/handle/123456789/4756
dc.identifier.urihttp://www.cris.uns.ac.rs/record.jsf?recordId=95722&source=NaRDuS&language=srsr
dc.identifier.urihttp://www.cris.uns.ac.rs/DownloadFileServlet/IzvestajKomisije144369517028599.pdf?controlNumber=(BISIS)95722&fileName=144369517028599.pdf&id=4385&source=NaRDuS&language=srsr
dc.description.abstractU disertaciji su opisane sinteze i fizičko-hemijske karakterizacije 32 kompleksa kobalta(III), nikla(II) i bakra(II) sa ligandima S-metilizotiosemikarbazonom 2-acetilpiridina (HL¹), bis(S-metilizotiosemikarbazonom) 2,6-diacetilpiridina (H₂L²), tiosemikarbazonom-S-metilizotiosemikarbazonom 2,6-diacetilpiridina (HL³), 1-adamantoilhidrazonom 2-acetilpiridina (HL⁴) i 1-adamantoilhidrazonom di(2-piridil)-ketona (HL⁵). Kako ligandi HL³, HL⁴ i HL⁵ do sada nisu bili sintetisani, dobijeni rezultati ujedno predstavljaju i prve iz njihove koordinacione hemije. Iako je sa S-metilizotiosemikarbazonom 2-acetilpiridina poznato nekoliko kompleksa, do sada nijedan od njih nije strukturno okarakterisan, tako da su rezultati prikazani u ovoj disertaciji dali jasnu sliku o načinima koordinacije HL¹. Takođe, kako je sa H₂L² poznat vrlo malo broj kompleksa, dobijeni rezultati su dali značajan doprinos razumevanju koordinacione hemije ovog liganda. Gotovo svi sintetisani kompleksi (njih 27 od 32) su strukturno okarakterisani metodom rendgenske kristalografije. Odabrana jedinjenja su ispitana metodama termičke analize, a utvrđena je njihova antimikrobna i citotoksična aktivnost.  sr
dc.description.abstractThis thesis describes syntheses and physico-chemical characterizations of 32 complexes of cobalt(III), nickel(II) and copper(II), with ligands 2-acetylpyridine S-methylisothiosemicarbazone (HL¹), 2,6-dicetylpyridine bis(S-methylisothiosemicarbazone) (H₂L²), thiosemicarbazone-S-methylisothiosemicarbazone 2,6-dicetylpyridine (HL³), 2-acetylpyridine 1-adamantoylhydrazone (HL⁴), and di(2-pyridil)-ketone 1-adamantoylhydrazone (HL⁵). Since the ligands HL³, HL⁴, and HL⁵ were not synthetized hitherto, the obtained results are the first regarding their coordination chemistry as well. Even though there are several complexes reported with 2-acetylpyridine S-methylisothiosemicarbazone as a ligand, none of them was structurally characterized. Therefore, here presented results gave clear insight into coordination modes of the HL¹. Moreover, since there is limited number of complexes with H₂L² reported hitherto, the obtained results gave significant contribution to understanding of its coordination chemistry. Almost each synthetized complex (27 out of 32) was structurally characterized by means of single crystal X-ray crystallography. The selected compounds were characterized by thermal analysis, and their antimicrobial and cytotoxic activity were determined.en
dc.languagesr (latin script)
dc.publisherУниверзитет у Новом Саду, Природно-математички факултетsr
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172014/RS//
dc.rightsopenAccessen
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.sourceУниверзитет у Новом Садуsr
dc.subjectKompleksna jedinjenjasr
dc.subjectComplexesen
dc.subjecthidrazonisr
dc.subjectkristalana strukturasr
dc.subjecttermičke i spektralne karakteristikesr
dc.subjectbiološka aktivnostsr
dc.subjecthydrazonesen
dc.subjectcrystal structureen
dc.subjectthermal and spectral characteristicsen
dc.subjectbio-logical activityen
dc.titleKompleksi Co(III), Ni(II) i Cu(II) sa hidrazonima nekih 2-piridil-ketonasr
dc.titleComplexes of Co(III), Ni(II) and Cu(II) with hydrazones of some 2-pyridyl-ke-tonesen
dc.typedoctoralThesisen
dc.rights.licenseBY-NC-ND
dcterms.abstractЛеовац Вукадин; Богдановић Горан; Јовановић Љиљана; Богдановић Горан; Мéсзáрос Сзéцсéнyи Каталин; Војиновић-Јешић Љиљана; Јоксовић Милан; Леовац Вукадин; Родић Марко; Комплекси Цо(ИИИ), Ни(ИИ) и Цу(ИИ) са хидразонима неких 2-пиридил-кетона; Комплекси Цо(ИИИ), Ни(ИИ) и Цу(ИИ) са хидразонима неких 2-пиридил-кетона;
dc.identifier.fulltexthttps://nardus.mpn.gov.rs/bitstream/id/38894/IzvestajKomisije355.pdf
dc.identifier.fulltexthttps://nardus.mpn.gov.rs/bitstream/id/38895/Disertacija355.pdf
dc.identifier.fulltexthttp://nardus.mpn.gov.rs/bitstream/id/38894/IzvestajKomisije355.pdf
dc.identifier.fulltexthttp://nardus.mpn.gov.rs/bitstream/id/38895/Disertacija355.pdf
dc.identifier.rcubhttps://hdl.handle.net/21.15107/rcub_nardus_4756


Files in this item

Thumbnail
Thumbnail

This item appears in the following Collection(s)

Show simple item record